Indian Journal of Advances in Chemical Science Volume: 5, Issue 4: , September 2017

 
             
   
   

ISSN No.: 2320-0898 (Print); 2320-0928 (Electronic)

DOI:  10.22607/IJACS.2017.504012

 

   

Research Article

 

      Synthesis and Spectral Characterization of Bismuth Dithiolate Derivatives of Disubstituted Diphenyldithiophosphates    
Atiya Syed*
ABSTRACT
 

The present work deals with the synthesis of four complexes with general formula [{(ArO)2PS2}Bi(SCH2CH2S)] (1-4), where Ar = 2,4-(CH3)2C6H3, 2,5-(CH3)2C6H3, 3,4-(CH3)2C6H3, and 3,5-(CH3)2C6H3, respectively. The reaction of [(ArO)2PS2Na], HSCH2CH2SH with Bi(NO3)3.5H2O in toluene in 1:1:1 molar stoichiometry afforded the complexes these complexes. These newly synthesized complexes have been characterized by elemental analysis, Fourier-transform infrared, and multinuclear nuclear magnetic resonance (NMR) (1H, 13C and 31P) NMR. The bismuth(III) atom is proposed to be surrounded by four sulfur atoms - two of dithiolate moiety and two from dithiophosphate moiety resulting in trigonal bipyramidal geometry with the fifth position being occupied by the lone pair of electrons.

     
     

Key words: Bismuth, Dithiophosphate, Dithiolate, Phosphorus.

 

 

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