Ions transport in nanofiltration (NF)
membranes was investigated by means of extended Nernst–Planck (ENP)
equation and Donnan relationship using as main variables, ions
strength, membrane charge density, membrane thickness, and with a
permeation flux range of 10−6–10−5 m/s. Four
different salt solutions were considered: NaCl, Na2SO4,
NaF, and MgSO4. Salt rejection coefficient is the main
index used for analyzing NF performance for both positive and
negative charged membranes. The model calculation showed an
excellent agreement with experimental data and high rejection
coefficient for Na2SO4 has been obtained.
Donnan effect was the major mechanism of rejection for different
salt solutions. |