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Indian Journal of Advances in Chemical Science Volume: 6,
Issue 4: , December 2018 |
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ISSN No.: 2320-0898 (Print);
2320-0928 (Electronic)
DOI:
10.22607/IJACS.2018.604006
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Research Article
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Electrochemical Studies of Indium
(III) and Nickel (II) Ions in the presence of New Schiff Base |
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M. V. N. V. Prasad
Gupta, Meer Althaf Ahamed, S. Ramanaiah, K. Sreenivasulu* |
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ABSTRACT |
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Schiff bases, resacetophenone imines
(renal proximal tubule [RPT]) ligand was synthesized using Tris (hydroxymethyl)
methylamine (Tris) and resacetophenone and has not been used so far
for the determination of lead and tellurium in trace quantities.
Effect of pH on wave height for In-(RPT) and Ni-(RPT) systems has
been studied at pH 6.5–11.0 in 0.1 M NaNO3, and 0.002%
Triton-X-100 which increases the stability of the complex. Effects
of ligand concentrations, height of mercury column, metal ion
concentrations on indium and nickel on wave height at pH 10.0 have
been studied. The author also investigates the metal-ligand ratio
and stability constants of tellurium-RPT by the reversible system. |
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Key words: Electro-chemical
study, Resacetophenone imine, Schiff base, Indium, Nickel and Deford
and Hume method. |
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[Download Full Article
PDF] |
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