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Indian Journal of Advances in Chemical Science, Volume: 10,
Issue : 1, January 2022 |
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ISSN No.: 2320-0898 (Print);
2320-0928 (Electronic)
DOI:
10.22607/IJACS.2022.1001002 |
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Article
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Study of
Electrical and Thermal Properties of Triazine Schiff’s Base
Complexes with Transition Metal(II) Ions |
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Kukalkar Madhuri, Murhekar
Gopalkrushna |
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ABSTRACT |
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In this investigation, the electrical
and thermal properties of newly synthesized Schiff bases from TRIPOD
with different
substituted aniline and complexes of TRIPOD-SBNA with transition
metal(II)ions were studied. An examination of the
thermograms of Schiff bases synthesized from TRIPOD with different
substituted aniline and ligand TRIPOD-SBNA with
transition metal(II)complexes indicates that they are with varying
thermal stability undergoing decomposition at different
temperatures. Their percent weight loss as computed from the
thermograms suggests that the final product of decomposition in them
corresponds to respective metal oxide. Further, the
thermogravimetric results offer supports to the composition of the
complex polymer conjugates. The electrical conductivity of Schiff
bases synthesized from TRIPOD with different substituted aniline and
ligand TRIPOD- SBNA with transition metal (II) complexes showed a
tendency to increase by increasing the temperature upto 407 K and
indicates their semiconducting behavior. |
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Key words: Complexes, TRIPOD, Tripodal Schiff’s Bases,
TRIPOD-SBNA. |
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