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Indian Journal of Advances in Chemical Science,
Volume: 11,
Issue : 2, April 2023 |
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ISSN No.: 2320-0898 (Print);
2320-0928 (Electronic)
DOI: 10.22607/IJACS.2023.1102005 |
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Research Article
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Design and
Synthesis of Disulfide-based Macrocycles and their Heavy Metal Ion
Complexation and Self-assembly Studies |
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Ishanki Bhardwaj*
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ABSTRACT |
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A set of disulfide-based macrocycles
C4-C8 with different spacer groups were synthesized. They possess
complexing abilities toward heavy metal ions such as Hg2+ and Cd2+.
C4 showed specific binding toward Hg2+, while C6 exhibited binding
toward Cd2+. Self-assembly analysis depicted their varied
morphologies dependent on spacer moiety and internal molecular
arrangement. |
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Key words: Macrocycle, Click reaction, Heavy metal sensors,
Self-assembly, Vesicles. |
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[Download Full Article
PDF] |
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