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Indian Journal of Advances in Chemical Science Volume: 6,
Issue 2: , April 2018 |
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ISSN No.: 2320-0898 (Print);
2320-0928 (Electronic)
DOI:
10.22607/IJACS.2018.602004
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Research Article
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Optical and Dielectric
Properties of Li+ Ion Conducting Solid Polymer Electrolyte |
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Shreedatta Hegde, V.
Ravindrachary*, S. D. Praveena, B. Guruswamy, Rohan N. Sagar
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ABSTRACT |
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Lithium ion (Li+) conducting solid
polymer electrolytes have been prepared by solution casting method.
The prepared films were characterized using different techniques.
Fourier-transform infrared result revealed complexation of dopant
with the polymer through interaction of Li+ ion of LiCl with O-H and
C=O group of polyvinyl alcohol (PVA). Ultraviolet-visible spectra
show the change in optical properties such as optical energy band
gap and activation energy with doping level. Dielectric studies
revealed non-Debye nature of polymer electrolytes. Electrical
properties revealed that the maximum dc conductivity of 2.28 × 10−4
S/cm has been obtained for 15 wt% LiCl doped PVA at room
temperature. |
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Key words: Chitosan,
Copper, Membrane, Nickel, Poly(Acrylic acid), Polyaniline. |
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[Download Full Article
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